|
工作地点:法国巴黎索邦大学
课题组介绍:http://www.ipcm.fr/bouteiller-laurent-777?lang=en#opennewwindow
项目介绍:csc与索邦大学(sorbonne université)的合作项目
招生类型:
1. 应届与往届硕士毕业生
招生要求:
1. 性格开朗,勤奋好学;
2. 仅考虑有机合成或均相催化背景的候选人,有超分子均相催化背景的学生更佳;
3. 有至少一篇一作的英文文章;
4. 需要与课题组一起申请csc。
研究内容:
Selectivity switchable catalyst for asymmetric cascade reactions
Our project is at the forefront of innovation in the field of homogeneous catalysis. In the domain of supramolecular catalysis, non-covalent interactions are designed between the partners of the catalytic reaction in order to build catalysts with new functions or modify the catalytic performance of an existing catalyst.[1] We propose a new approach in which hydrogen-bonded supramolecular polymers, formed by means of non-covalent interactions between structurally-simple monomers, are used as a scaffold for catalysis. As a proof-of-concept, we performed asymmetric reactions by means of intrinsically achiral metal complexes positioned at the periphery of chiral assemblies. These chiral assemblies are formed by mixing chiral and achiral BTA monomers.[2-5] The topic of this thesis concerns the use of selectivity switchable catalysts in stereoselective cascade reactions, following our recently published papers.
Major publications in the domain:
[1] M. Raynal, P. Ballester, A. Vidal-Ferran, P. W. N. M. van Leeuwen Chem. Soc. Rev. 2014, 43, 1660
[2] A. Desmarchelier, X. Caumes, M. Raynal, A. Vidal-Ferran, P. W. N. M. van Leeuwen, L. Bouteiller J. Am. Chem. Soc. 2016, 138, 4908
[3] J. M. Zimbron, X. Caumes, Y. Li, C. M. Thomas, M. Raynal, L. Bouteiller Angew. Chem. Int. Ed. 2017, 56, 14016
[4] Y. Li, X. Caumes, M. Raynal, L. Bouteiller Chem. Commun. 2019, 55, 2162
[5] Y. Li, L. Bouteiller, M. Raynal ChemCatChem 2019, 11, 5212
A strong expertise in organic synthesis and practical experience in homogeneous catalysis is required.
团队优势:
1. 法国最好的大学(居里夫妇的母校)
2. 超一流的实验条件与强大的公共测试/仪器平台(经培训后可自主操作);
3. 年轻的团队,和谐的师生关系。
有意向攻读读索邦大学博士学位请直接联系
dr. laurent bouteiller (laurent.bouteiller@sorbonne-universite.fr)
请各位同学注意
bouteiller教授这次需要招收具有较强有机化学背景的学生!从事等研究课体是关于超分子手性催化,需要较强的小分子合成或均相催化的专业背景!
|
欢迎来到水木紫荆书院!
|